Rahul Verma will replace Nancy Powell, who resigned after a damaging row over diplomat Devyani Khobragade.
After a clinical display with the ball, India need only 128 runs to win the game and go 2-0 up in the series.
Indian bowlers conceded 258 runs for the last four wickets and struggled to clean up the Aussie tail.
Smith has become the fifth Australian player to record a century in his maiden Test innings as skipper.
India again found it difficult to get rid of the tail quickly and allowed the Aussies to get a handsome lead of 97.
Rohit is yet to post a fifty in eight Test innings -his last half-century being 72 vs New Zealand at Auckland
Hazlewood, 23, became the 33rd Aussie to take a five-for on Test debut & 16th to do so in his debut innings.
Umesh’s fiery bowling, Warner’s innings, Rogers gritty innings and more talking points from Day 2’s play.
The match hangs in balance going into Day 3 as skipper Smith shepherded his side with an unbeaten knock of 65.
Pacers Josh Hazlewood and Mitchell Starc also needed treatment for cramps and muscle fatigue.
Funnily enough, Murali Vijay had to be told by Rahane, that he had got to his three-figure mark.
While Vijay was out after scoring his hundred, Rahane is still there in the middle and doing a fine job with Rohit Sharma.
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With trauma of Pakistan loss still fresh in their minds, India lose 2-1 in bronze-medal playoff.
Muhammad Tousiq and Ali Amjad will miss the final later on Sunday against Germany.